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Kevin Maxwell will head the Prince George's County Public School system.
Curtis Valentine, Daniel Kaufman and Beverly Anderson will work alongside nine other elected school board members.
On Saturday, County Executive Rushern Baker appointed a new Board of Education chairman.
More than 150 people have applied to serve on the Prince George's County school board, as part of the reform process approved by legislation in Annapolis that takes effect next month.
Alvin L. Crawley will resign as the interim superintendent of Prince George's County Public Schools, Maryland's second largest school system, effective June 3.